Cadmium selenate - Wiki slovník

Cadmium selenate
Identifiers
CAS Number	13814-62-5 anhydrous ; 20861-74-9 monohydrate ; 10060-09-0 dihydrate ;
3D model (JSmol)	Interactive image;
ChemSpider	146042;
ECHA InfoCard	100.034.060
EC Number	237-481-3;
PubChem CID	166912;
UNII	3U4HEE3NCC;
CompTox Dashboard (EPA)	DTXSID60884646 ;
	InChI InChI=1S/Cd.H2O4Se/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2 Key: VTFKXHQTGNWIJW-UHFFFAOYSA-L;
	SMILES .(=O)(=O);
Properties
Chemical formula	CdO4Se
Molar mass	255.381 g·mol−1
Appearance	colourless solid (dihydrate)
Density	3.62 g·cm−3 (dihydrate)
Melting point	100 °C (dihydrate decomposes)
Solubility in water	70.5 g·l−1
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H301, H331, H373, H410
Precautionary statements	P260, P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P319, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions	cadmium sulfate; cadmium selenite
Other cations	zinc selenate; mercury selenate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Cadmium selenate is a selenate of cadmium, with the chemical formula CdSeO₄.

Preparation

Cadmium selenate can be formed by the reaction of cadmium oxide and selenic acid. The product is a mixture of monohydrate and dihydrate.^[4]

CdO + H₂SeO₄ → CdSeO₄ + H₂O

Properties

Cadmium selenate dihydrate is a colorless solid. At 100 °C, the dihydrate releases water of crystallization to form cadmium selenate monohydrate.^[1] The monohydrate is monoclinic with space group P2₁/c (no. 14),^[4] while the dihydrate is orthorhombic, with space group Pbca (no. 61).^[5]

References

^ ^a ^b R. J. Meyer (2013), Cadmium System-Nummer 33, Springer-Verlag, p. 133, ISBN 978-3-662-11295-3
^ ^a ^b ^c William M. Haynes (2016), CRC Handbook of Chemistry and Physics, 94th Edition, CRC Press, p. 54, ISBN 978-1-4665-7115-0
^ "Cadmium selenate". pubchem.ncbi.nlm.nih.gov.
^ ^a ^b Stålhandske, C. (1981-11-15). "Structure of cadmium selenate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 37 (11): 2055–2057. Bibcode:1981AcCrB..37.2055S. doi:10.1107/S0567740881007942.
^ H.U.v. Vogel (2013), Chemiker-Kalender, Springer-Verlag, p. 78, ISBN 978-3-662-06237-1

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[R._J._Meyer-1] R. J. Meyer (2013), Cadmium System-Nummer 33, Springer-Verlag, p. 133, ISBN 978-3-662-11295-3

[William_M._Haynes-2] William M. Haynes (2016), CRC Handbook of Chemistry and Physics, 94th Edition, CRC Press, p. 54, ISBN 978-1-4665-7115-0

[3] "Cadmium selenate". pubchem.ncbi.nlm.nih.gov.

[Stålhandske-4] Stålhandske, C. (1981-11-15). "Structure of cadmium selenate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 37 (11): 2055–2057. Bibcode:1981AcCrB..37.2055S. doi:10.1107/S0567740881007942.

[H.U.v._Vogel-5] H.U.v. Vogel (2013), Chemiker-Kalender, Springer-Verlag, p. 78, ISBN 978-3-662-06237-1

[1]

[2]

[3]

[4]

[5]

v t e Cadmium compounds
Cadmium(I)	Cd₂(AlCl₄)₂
Cadmium(II)	Cd(BF₄)₂ CdF₂ CdCl₂ CdBr₂ CdI₂ Cd(CN)₂ CdH₂ CdO CdS CdSe CdTe Cd(OH)₂ Cd₃N₂ Cd(NO₃)₂ CdSO₄ CdSeO₄ CdCrO₄ CdWO₄ CdTeO₃ Cd(C₃H₅O₃)₂ Cd₃As₂ Cd₃P₂ CsCdCl₃ CsCdBr₃ Cd(CH₃CO₂)₂ Cd(O₂CC₁₇H₃₅)₂

Identifiers

CAS Number	13814-62-5 anhydrous^Y 20861-74-9 monohydrate^Y 10060-09-0 dihydrate^Y
3D model (JSmol)	Interactive image
ChemSpider	146042
ECHA InfoCard	100.034.060
EC Number	237-481-3
PubChem CID	166912
UNII	3U4HEE3NCC
CompTox Dashboard (EPA)	DTXSID60884646
InChI InChI=1S/Cd.H2O4Se/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2 Key: VTFKXHQTGNWIJW-UHFFFAOYSA-L
SMILES .(=O)(=O)
Properties
Chemical formula	CdO₄Se
Molar mass	255.381 g·mol⁻¹
Appearance	colourless solid (dihydrate)^[1]
Density	3.62 g·cm⁻³ (dihydrate)^[2]
Melting point	100 °C (dihydrate decomposes)^[2]
Solubility in water	70.5 g·l⁻¹ ^[2]
Hazards
GHS labelling:^[3]
Pictograms
Signal word	Warning
Hazard statements	H301, H331, H373, H410
Precautionary statements	P260, P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P319, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions	cadmium sulfate cadmium selenite
Other cations	zinc selenate mercury selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references