Platinum pentafluoride - Wiki slovník

Platinum pentafluoride
Names
	IUPAC name Platinum(V) fluoride
	Other names Platinum pentafluoride
Identifiers
CAS Number	13782-84-8;
3D model (JSmol)	monomer: Interactive image; tetramer: Interactive image;
CompTox Dashboard (EPA)	DTXSID101045630 ;
	InChI InChI=1S/5FH.Pt/h5*1H;/q;;;;;+5/p-5 Key: YKYDLLIWWRPCHN-UHFFFAOYSA-I;
	SMILES monomer: F(F)(F)(F)F; tetramer: F1(F)(F)(F)(F)(F)(F)(F)(F)(F)(F)(F)(1)(F)(F)(F)F;
Properties
Chemical formula	F5Pt
Molar mass	290.07
Appearance	red solid
Melting point	75–76 °C (167–169 °F; 348–349 K)
Boiling point	300–305 °C (572–581 °F; 573–578 K)
Related compounds
Related compounds	Platinum(IV) fluoride ; Platinum(VI) fluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Platinum pentafluoride is the inorganic compound with the empirical formula PtF₅. This red volatile solid has rarely been studied but is of interest as one of the few binary fluorides of platinum, i.e., a compound containing only Pt and F. It is hydrolyzed in water.^[1]

The compound was first prepared by Neil Bartlett by fluorination of platinum dichloride above 350 °C (below that temperature, only PtF₄ forms).^[1]

Its structure consists of a tetramer, very similar to that of ruthenium pentafluoride. Within the tetramers, each Pt adopts octahedral molecular geometry, with two bridging fluoride ligands.^[2]

References

^ ^a ^b Bartlett, N.; Lohmann, D. H. (1960). "Two New Fluorides of Platinum". Proceedings of the Chemical Society. London: 14–15. doi:10.1039/PS9600000001.
^ Mueller, B. G.; Serafin, M. (1992). "Single-crystal investigations on PtF₄ and PtF₅". European Journal of Solid State Inorganic Chemistry. 29 (4–5): 625–633. doi:10.1002/chin.199245006.^{[full citation needed]}

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[NB-1] Bartlett, N.; Lohmann, D. H. (1960). "Two New Fluorides of Platinum". Proceedings of the Chemical Society. London: 14–15. doi:10.1039/PS9600000001.

[r1-2] Mueller, B. G.; Serafin, M. (1992). "Single-crystal investigations on PtF₄ and PtF₅". European Journal of Solid State Inorganic Chemistry. 29 (4–5): 625–633. doi:10.1002/chin.199245006.^{[full citation needed]}

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